Sensitivity Issues in Step-Scan FT-IR Spectrometry 
It is interesting to calculate the highest frequency
of multiplicative noise that will just begin to affect the spectrum. That is, the
frequency which will just begin to mix adjacent spectral elements rather than convolving
noise across the entire spectrum. For a rapid-scan measurement with 5 kHz modulation of
the laser, it is 1.3 Hz. Not coincidentally, this is the frequency that goes through
exactly one cycle during the interferogram measurement time. The same observations are
also true for step-scan measurements, but the frequency is 5000 times lower, or 0.24
milliHertz.
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