Sensitivity Issues in Step-Scan FT-IR Spectrometry 
The first clue indicates that the noise is low in
frequency. The second and third clues both indicate that the noise sources are
multiplicative; that is, the noise scales linearly with the signal. The SNR of spectra
measured using a chopper (AM) is much worse than the SNR of spectra measured by phase
modulation (PM). PM is a derivative technique which removes from the detected signal a
large DC component of radiation not modulated by the interferometer. This DC component can
carry multiplicative noise, so it is desirable to remove it. As noted in Slide 4, the
noise level in dynamic difference spectra is 1 to 2 orders of magnitude lower than in the
corresponding single-beam spectra. This also points to a multiplicative noise source which
is discriminated by the second demodulation. The final clue indicates that a significant
part of the noise is below 1 Hz. In certain experiments the averaging time, t, at each
step was increased from 0.5 to 8 seconds, and resulted in an increase in SNR significantly
greater than the expected Öt.
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